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Forging 904L stainless steel forgings forging rod forgings square forgings manufacturing
904L (N08904, 14539) super austenitic stainless steel contains 14.0-18.0% chromium, 24.0-26.0% nickel, and 4.5% molybdenum. 904L super austenitic stainless steel is a low-carbon, high-nickel, molybdenum austenitic stainless acid-resistant steel, which is a proprietary material introduced from H.S. Company of France. It has good activation-passivation transformation ability, excellent corrosion resistance, good corrosion resistance in non-oxidizing acids such as sulfuric acid, acetic acid, formic acid, and phosphoric acid, good pitting resistance in neutral chloride ion media, and good crevice corrosion resistance and stress corrosion resistance. It is suitable for various concentrations of sulfuric acid below 70°C, and has good corrosion resistance in acetic acid of any concentration and any temperature under normal pressure, and mixed acid of formic acid and acetic acid.
Super austenitic stainless steel 904L (00Cr20Ni25Mo4.5Cu; UNS: N08904; EN: 1.4539) is a high-alloy austenitic stainless steel with low carbon content. It has good corrosion resistance in dilute sulfuric acid and is designed for harsh corrosive environments. It has a high chromium content and sufficient nickel content. The addition of copper makes it highly resistant to acid, especially chloride crevice corrosion and stress corrosion cracking. It is not easy to have pitting and cracks. The pitting resistance is slightly better than other steel grades. It has good machinability and weldability and can be used for pressure vessels.
Metallographic structure of 904L stainless steel:
904L is a completely austenitic structure. Compared with austenitic
stainless steel with a high molybdenum content, 904L is insensitive
to the precipitation of ferrite and α phase.
Physical and mechanical properties:
Density: 8.0g/cm3. Tensile strength: σb≥520Mpa. Elongation: δ≥35%.
Corrosion resistance of 904L stainless steel:
Since the carbon content of 904L is very low (maximum 0.020%), no
carbide will precipitate under general heat treatment and welding.
This eliminates the risk of intergranular corrosion after general
heat treatment and welding. Due to the high chromium, nickel and
molybdenum content and the addition of copper, 904L can be
passivated even in a reducing environment such as sulfuric acid and
formic acid. The high nickel content makes it have a lower
corrosion rate in the active state. In pure sulfuric acid in the
concentration range of 0~98%, the operating temperature of 904L can
be as high as 40 degrees Celsius. In pure phosphoric acid in the
concentration range of 0-85%, its corrosion resistance is very
good. In industrial phosphoric acid produced by wet process,
impurities have a strong influence on corrosion resistance. Among
all kinds of phosphoric acid, 904L has better corrosion resistance
than ordinary stainless steel. In strongly oxidizing nitric acid,
904L has lower corrosion resistance than high-alloyed steels
without molybdenum. In hydrochloric acid, the use of 904L is
limited to lower concentrations of 1-2%. In this concentration
range. 904L has better corrosion resistance than conventional
stainless steel. 904L steel has high resistance to pitting
corrosion. Its resistance to crevice corrosion in chloride
solutions is also very good. The high nickel content of 904L
reduces the corrosion rate in pits and crevices. Ordinary
austenitic stainless steels may be sensitive to stress corrosion in
a chloride-rich environment at temperatures above 60 degrees
Celsius. This sensitization can be reduced by increasing the nickel
content of stainless steel. Due to the high nickel content, 904L
has high resistance to stress corrosion cracking in chloride
solutions, concentrated hydroxide solutions and hydrogen
sulfide-rich environments.
Alloy | % | Cr | Ni | Mo | Cu | Fe | C | Mn | Si | P | S |
904L | Minimum | 19 | 23 | 4 | 1 | margin | - | - | - | - | - |
- | maximum | 23 | 28 | 5 | 2 | - | 0.02 | 2 | 1 | 0.045 | 0.035 |
Density | 8.0 g/cm3 |
Melting point | 1300-1390 ℃ |
Alloy state | tensile strength Rm N/mm2 | Yield StrengthRP0.2N/mm2 | Elongation A5 % |
904L | 490 | 216 | 35 |
904L uses, application range, and application areas include:
* Petroleum and petrochemical equipment, such as reactors in
petrochemical equipment.
* Storage and transportation equipment for sulfuric acid, such as
heat exchangers.
* Flue gas desulfurization equipment in power plants, the main use
parts are: tower body, flue, baffle plate, internal parts, spray
system, etc. of the absorption tower.
* Scrubbers and fans in organic acid treatment systems.
* Seawater treatment equipment, seawater heat exchangers,
papermaking industry equipment, sulfuric acid and nitric acid
equipment, acid making, pharmaceutical industry and other chemical
equipment, pressure vessels, food equipment.
* Pharmaceutical factories: centrifuges, reactors, etc.
* Plant foods: soy sauce tanks, cooking wine, salt tanks, equipment
and dressings.
* 904L is a matching steel grade for highly corrosive media such as
dilute sulfuric acid.